|Table of Contents|

State-of-the-art review on influence of retarders on performance of alkali-activated materials(PDF)

《建筑科学与工程学报》[ISSN:1673-2049/CN:61-1442/TU]

Issue:
2023年05期
Page:
20-31
Research Field:
综述
Publishing date:

Info

Title:
State-of-the-art review on influence of retarders on performance of alkali-activated materials
Author(s):
XIE Jianhe LI Liming HUANG Junjian FENG Yuan ZHANG Baifa
(School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, Guangdong, China)
Keywords:
alkali-activated material retarder setting time fluidity compressive strength
PACS:
TU528
DOI:
10.19815/j.jace.2021.12074
Abstract:
Taking common retarders in engineering as the research object, the reaction mechanism of retarders in alkaline-activated materials(AAM)system was discussed. By establishing an experimental database of existing literature both domestically and internationally, the influence of retarders on the properties of AAM, such as setting time, fluidity, and compressive strength, was elucidated. The impact of retarders on the environment was evaluated and a cost analysis of retarders suitable for AAM was conducted, providing a reference for the effectiveness and applicability of retarders in AAM engineering applications. The shortcomings of existing research were pointed out and the directions for further research on AAM retarders were provided. The results show that barium salt, zinc salt, BCH, VAE emulsion and borax have good retarding effects, among which barium salt and zinc salt have significant retarding effects, and the setting time increases with the increase of the dosage. An appropriate amount of barium chloride and borax can slightly improve the fluidity of AAM. Although sodium gluconate cannot effectively prolong the setting time of AAM, it can greatly improve fluidity. Moderate addition of barium salt, zinc salt, borax, phosphoric acid, and phosphate will not have a significant impact on the strength, but when the dosage exceeds 5%, barium salt and zinc salt will cause serious compressive strength loss of AAM. AAM has excellent solidification effect on heavy metals, so AAM mixed with an apporopriate amount of heavy metal ion retarders will not cause harm to the environment. When using a retarder to regulate the setting time of slag based polymer concrete, in order to achieve the same retarding effect, the cost of using barium chloride is 0.47 times that of zinc nitrate and 0.4 times that of barium nitrate, respectively.

References:

[1] MOHAMED O A.A review of durability and strength characteristics of alkali-activated slag concrete[J].Materials,2019,12(8):1198.
[2]SHI C J,QU B,PROVIS J L.Recent progress in low-carbon binders[J].Cement and Concrete Research,2019,122:227-250.
[3]HASSAN A,ARIF M,SHARIQ M.A review of properties and behaviour of reinforced geopolymer concrete structural elements — a clean technology option for sustainable development[J].Journal of Cleaner Production,2020,245:118762.
[4]MO K H,ALENGARAM U J,JUMAAT M Z.Structural performance of reinforced geopolymer concrete members:a review[J].Construction and Building Materials,2016,120:251-264.
[5]ZHANG B F,GUO H Z,DENG L L,et al.Undehydrated kaolinite as materials for the preparation of geopolymer through phosphoric acid-activation[J].Applied Clay Science,2020,199:105887.
[6]ZHANG B F,GUO H Z,YUAN P,et al.Geopolymerization of halloysite via alkali-activation:dependence of microstructures on precalcination[J].Applied Clay Science,2020,185:105375.
[7]刘进强,郝 斌,郁建元,等.无熟料碱激发胶凝材料的研究进展[J].材料导报,2014,28(增1):351-354.
LIU Jinqiang,HAO Bin,YU Jianyuan,et al.Research progress on clinker-free alkali-activated binding materials[J].Materials Review,2014,28(S1):351-354.
[8]XIE J H,WANG J J,RAO R,et al.Effects of combined usage of GGBS and fly ash on workability and mechanical properties of alkali activated geopolymer concrete with recycled aggregate[J].Composites Part B:Engineering,2019,164:179-190.
[9]XIE J H,WANG J J,ZHANG B X,et al.Physicochemical properties of alkali activated GGBS and fly ash geopolymeric recycled concrete[J].Construction and Building Materials,2019,204:384-398.
[10]XIE J H,ZHAO J B,WANG J J,et al.Sulfate resistance of recycled aggregate concrete with GGBS and fly ash-based geopolymer[J].Materials,2019,12(8):1247.
[11]YARAGAL S C,CHETHAN KUMAR B,JITIN C.Durability studies on ferrochrome slag as coarse aggregate in sustainable alkali activated slag/fly ash based concretes[J].Sustainable Materials and Technologies,2020,23:e00137.
[12]吴 萌,姬永生,展光美,等.低温环境下赤泥地聚合物抗硫酸盐侵蚀机理研究[J].材料导报,2016,30(18):122-127.
WU Meng,JI Yongsheng,ZHAN Guangmei,et al.Mechanism study on red mud geopolymer to sulfate attack at low temperature[J].Materials Review,2016,30(18):122-127.
[13]DING Y,DAI J G,SHI C J.Mechanical properties of alkali-activated concrete:a state-of-the-art review[J].Construction and Building Materials,2016,127:68-79.
[14]万小梅,张 宇,赵铁军,等.碱激发矿渣混凝土的力学性能[J].材料导报,2018,32(12):2091-2095.
WAN Xiaomei,ZHANG Yu,ZHAO Tiejun,et al.Mechanical properties of alkali-activated slag concrete[J].Materials Review,2018,32(12):2091-2095.
[15]RATTANASAK U,PANKHET K,CHINDAPRASIRT P.Effect of chemical admixtures on properties of high-calcium fly ash geopolymer[J].International Journal of Minerals,Metallurgy,and Materials,2011,18(3):364-369.
[16]NATH P,SARKER P K.Effect of GGBFS on setting,workability and early strength properties of fly ash geopolymer concrete cured in ambient condition[J].Construction and Building Materials,2014,66:163-171.
[17]RAFEET A,VINAI R,SOUTSOS M,et al.Guidelines for mix proportioning of fly ash/GGBS based alkali activated concretes[J].Construction and Building Materials,2017,147:130-142.
[18]季 韬,张检梅,王灿强.粉煤灰和炉渣对碱激发镍渣胶凝材料流动度和强度的影响[J].混凝土与水泥制品,2019(12):87-90,97.
JI Tao,ZHANG Jianmei,WANG Canqiang.Effect of fly ash and incineration slag on the fluidity and strength of alkali-activated nickel slag cementitious material[J].China Concrete and Cement Products,2019(12):87-90,97.
[19]CHOI S,LEE K M.Influence of Na2O content and Ms(SiO2/Na2O)of alkaline activator on workability and setting of alkali-activated slag paste[J].Materials,2019,12(13):2072.
[20]WANG W C,WANG H Y,LO M H.The engineering properties of alkali-activated slag pastes exposed to high temperatures[J].Construction and Building Materials,2014,68:409-415.
[21]王宇轩,周国安,陈佩圆,等.激发剂组成对碱激发-矿渣水泥砂浆变形及力学性能的影响[J].新型建筑材料,2017,44(8):1-4,17.
WANG Yuxuan,ZHOU Guoan,CHEN Peiyuan,et al.Influence of activator with different compositions on the deformation and mechanical properties of alkali-activated slag cement mortar[J].New Building Materials,2017,44(8):1-4,17.
[22]孙小巍,吴陶俊.碱激发矿渣胶凝材料的试验研究[J].硅酸盐通报,2014,33(11):3036-3040.
SUN Xiaowei,WU Taojun.Experimental research of alkali-activated slag cementitious material[J].Bulletin of the Chinese Ceramic Society,2014,33(11):3036-3040.
[23]张志强,周栋梁,李付刚,等.碱-矿渣水泥缓凝物质的选择研究[J].混凝土,2008(8):63-64,68.
ZHANG Zhiqiang,ZHOU Dongliang,LI Fugang,et al.Selection of retarder of alkali activated slag cement[J].Concrete,2008(8):63-64,68.
[24]乔 飞,余其俊,赵三银,等.适应于碱激发碳酸盐矿-矿渣胶凝材料的缓凝剂研究[J].长江科学院院报,2007,24(1):36-39,43.
QIAO Fei,YU Qijun,ZHAO Sanyin,et al.Research on retarder available for alkali activated carbonatite-slag cementitious material[J].Journal of Yangtze River Scientific Research Institute,2007,24(1):36-39,43.
[25]SHAH S F A,CHEN B,ODERJI S Y,et al.Improvement of early strength of fly ash-slag based one-part alkali activated mortar[J].Construction and Building Materials,2020,246:118533.
[26]ODERJI S Y,CHEN B,SHAKYA C,et al.Influence of superplasticizers and retarders on the workability and strength of one-part alkali-activated fly ash/slag binders cured at room temperature[J].Construction and Building Materials,2019,229:116891.
[27]HE J,ZHENG W H,BAI W B,et al.Effect of reactive MgO on hydration and properties of alkali-activated slag pastes with different activators[J].Construction and Building Materials,2021,271:121608.
[28]LI N,SHI C J,ZHANG Z H.Understanding the roles of activators towards setting and hardening control of alkali-activated slag cement[J].Composites Part B:Engineering,2019,171:34-45.
[29]ZHANG L L,JI Y S,JUN L,et al.Effect of retarders on the early hydration and mechanical properties of reactivated cementitious material[J].Construction and Building Materials,2019,212:192-201.
[30]樊晓丹,李玉祥,王少剑,等.碱激发超细矿渣粉制备灌浆料的缓凝问题研究[J].混凝土,2014(10):81-85.
FAN Xiaodan,LI Yuxiang,WANG Shaojian,et al.Study on retardation of preparing grouting material by alkali-activated fine slag powder[J].Concrete,2014(10):81-85.
[31]姚 运.外加剂对碱激发粉煤灰材料性能的影响研究[J].粉煤灰综合利用,2018,31(3):15-17,21.
YAO Yun.Study on the effect of admixtures on the properties of alkali activated fly ash[J].Fly Ash Comprehensive Utilization,2018,31(3):15-17,21.
[32]刘 荣,马玉玮,李 源,等.外加剂对碱激发粉煤灰/矿渣胶凝材料早期性能的影响[J].科学技术与工程,2017,17(16):107-113.
LIU Rong,MA Yuwei,LI Yuan,et al.The effect of admixtures on early-age properties of alkali-activated fly ash/slag[J].Science Technology and Engineering,2017,17(16):107-113.
[33]CONG X Y,ZHOU W,GENG X R,et al.Low field NMR relaxation as a probe to study the effect of activators and retarders on the alkali-activated GGBFS setting process[J].Cement and Concrete Composites,2019,104:103399.
[34]NAJIMI M,GHAFOORI N,SHARBAF M.Alkali-activated natural pozzolan/slag binders:limitations and remediation[J].Magazine of Concrete Research,2020,72(18):919-935.
[35]SUN C,SUN J W,WANG D M.Effect of tartaric acid on the early hydration of NaOH-activated slag paste[J].Journal of Thermal Analysis and Calorimetry,2021,144(1):41-50.
[36]余其俊,赵三银,黄家琪,等.碱激发碳酸盐矿-矿渣胶凝-灌浆材料缓凝与流动性能的改善[J].硅酸盐学报,2005,33(7):871-875.
YU Qijun,ZHAO Sanyin,HUANG Jiaqi,et al.Retardation of gelation and improvement of flowability for alkali-activated carbonatite slag cementitious-grouting material[J].Journal of the Chinese Ceramic Society,2005,33(7):871-875.
[37]张 烁,潘志华.化学物质对碱-矿渣水泥凝结时间和强度性能的影响[J].混凝土,2010(9):68-70,73.
ZHANG Shuo,PAN Zhihua.Effect of chemical substances on setting time and strength development of alkali-activated slag cement[J].Concrete,2010(9):68-70,73.
[38]KUSBIANTORO A,IBRAHIM M S,MUTHUSAMY K,et al.Development of sucrose and citric acid as the natural based admixture for fly ash based geopolymer[J].Procedia Environmental Sciences,2013,17:596-602.
[39]KARTHIK A,SUDALAIMANI K,VIJAYA KUMAR C T.Investigation on mechanical properties of fly ash-ground granulated blast furnace slag based self curing bio-geopolymer concrete[J].Construction and Building Materials,2017,149:338-349.
[40]KALINA L,BILEK V,NOVOTNY R,et al.Effect of Na3PO4 on the hydration process of alkali-activated blast furnace slag[J].Materials,2016,9(5):395.
[41]LEE N K,LEE H K.Setting and mechanical properties of alkali-activated fly ash/slag concrete manufactured at room temperature[J].Construction and Building Materials,2013,47:1201-1209.
[42]CHI M.Effects of dosage of alkali-activated solution and curing conditions on the properties and durability of alkali-activated slag concrete[J].Construction and Building Materials,2012,35:240-245.
[43]张武龙,杨长辉,杨 凯,等.磷酸钠-水玻璃对碱矿渣水泥水化行为的影响[J].建筑材料学报,2016,19(5):803-809,831.
ZHANG Wulong,YANG Changhui,YANG Kai,et al.Effect of sal perlatum-water glass on the hydration behavior of alkali-activated slag cements[J].Journal of Building Materials,2016,19(5):803-809,831.
[44]REVATHI T,JEYALAKSHMI R.Fly ash-GGBS geopolymer in boron environment:a study on rheology and microstructure by ATR FT-IR and MAS NMR[J].Construction and Building Materials,2021,267:120965.
[45]ODERJI S Y,CHEN B,SHAKYA C,et al.Influence of superplasticizers and retarders on the workability and strength of one-part alkali-activated fly ash/slag binders cured at room temperature[J].Construction and Building Materials,2019,229:116891.
[46]SINHA A K,TALUKDAR S.Enhancement of the properties of silicate activated ultrafine-slag based geopolymer mortar using retarder[J].Construction and Building Materials,2021,313:125380.
[47]ZHANG L L,JI Y S,LI J,et al.Effect of retarders on the early hydration and mechanical properties of reactivated cementitious material[J].Construction and Building Materials,2019,212:192-201.
[48]LI Z F,YOU H,GAO Y F,et al.Effect of ultrafine red mud on the workability and microstructure of blast furnace slag-red mud based geopolymeric grouts[J].Powder Technology,2021,392:610-618.
[49]陈 伟,金 浪,范剑锋,等.VAE乳液缓凝碱激发胶凝材料水化机理研究[J].硅酸盐通报,2016,35(6):1682-1687.
CHEN Wei,JIN Lang,FAN Jianfeng,et al.Hydration mechanism of alkali activated binder retarded with VAE emulsion[J].Bulletin of the Chinese Ceramic Society,2016,35(6):1682-1687.
[50]石 鑫,徐玲玲,冯 涛,等.水分散聚合物乳液改性水泥砂浆的研究进展[J].硅酸盐通报,2021,40(8):2497-2507.
SHI Xin,XU Lingling,FENG Tao,et al.Research progress of water dispersed polymer emulsion modified cement mortar[J].Bulletin of the Chinese Ceramic Society,2021,40(8):2497-2507.
[51]GARG N,WHITE C E.Mechanism of zinc oxide retardation in alkali-activated materials:an in situ X-ray pair distribution function investigation[J].Journal of Materials Chemistry A,2017,5(23):11794-11804.
[52]诸华军,姚 晓,张祖华,等.偏高岭土-矿渣基地聚合物缓凝剂的性能研究[J].建筑材料学报,2012,15(3):416-421.
ZHU Huajun,YAO Xiao,ZHANG Zuhua,et al.Study of retarder properties for metakaolin-slag geopolymer[J].Journal of Building Materials,2012,15(3):416-421.
[53]RATTANASAK U,PANKHET K,CHINDAPRASIRT P.Effect of chemical admixtures on properties of high-calcium fly ash geopolymer[J].International Journal of Minerals,Metallurgy,and Materials,2011,18(3):364-369.
[54]ZHAO Y L,QIU J P,ZHANG S Y,et al.Effect of sodium sulfate on the hydration and mechanical properties of lime-slag based eco-friendly binders[J].Construction and Building Materials,2020,250:118603.
[55]MOHSEN A,ABDEL-GAWWAD H A,RAMADAN M.Performance,radiation shielding,and anti-fungal activity of alkali-activated slag individually modified with zinc oxide and zinc ferrite nano-particles[J].Construction and Building Materials,2020,257:119584.
[56]ASSI L N,DEAVER E E,ZIEHL P.Using sucrose for improvement of initial and final setting times of silica fume-based activating solution of fly ash geopolymer concrete[J].Construction and Building Materials,2018,191:47-55.
[57]ASSI L N,DEAVER E E,ZIEHL P.Using sucrose for improvement of initial and final setting times of silica fume-based activating solution of fly ash geopolymer concrete[J].Construction and Building Materials,2018,191:47-55.
[58]NAZARI A,MAGHSOUDPOUR A,SANJAYAN J G.Characteristics of boroaluminosilicate geopolymers[J].Construction and Building Materials,2014,70:262-268.
[59]CHANG J J,YEIH W,HUNG C C.Effects of gypsum and phosphoric acid on the properties of sodium silicate-based alkali-activated slag pastes[J].Cement and Concrete Composites,2005,27(1):85-91.
[60]危险废物鉴别标准 浸出毒性鉴别:GB 5085.3—2007[S].北京:中国环境出版社,2007.
Identification standards for hazardous wastes — identification for extraction toxicity:GB 5085.3—2007[S].Beijing:China Environmental Science Press,2007.
[61]EL-ESWED B I.Chemical evaluation of immobilization of wastes containing Pb,Cd,Cu and Zn in alkali-activated materials:a critical review[J].Journal of Environmental Chemical Engineering,2020,8(5):104194.
[62]HUANG X,HUANG T,LI S,et al.Immobilization of chromite ore processing residue with alkali-activated blast furnace slag-based geopolymer[J].Ceramics International,2016,42(8):9538-9549.
[63]ZHANG P P,MUHAMMAD F,YU L,et al.Self-cementation solidification of heavy metals in lead-zinc smelting slag through alkali-activated materials[J].Construction and Building Materials,2020,249:118756.
[64]WAIJAREAN N,MACKENZIE K J D,ASAVAPISIT S,et al.Synthesis and properties of geopolymers based on water treatment residue and their immobilization of some heavy metals[J].Journal of Materials Science,2017,52(12):7345-7359.
[65]SHIOTA K,NAKAMURA T,TAKAOKA M,et al.Stabilization of lead in an alkali-activated municipal solid waste incineration fly ash-pyrophyllite-based system[J].Journal of Environmental Management,2017,201:327-334.
[66]WAIJAREAN N,ASAVAPISIT S,SOMBATSOMPOP K.Strength and microstructure of water treatment residue-based geopolymers containing heavy metals[J].Construction and Building Materials,2014,50:486-491.

Memo

Memo:
-
Last Update: 2023-09-01