|本期目录/Table of Contents|

[1]赵燕茹,李龙,关鹤,等.荷载与碳化共同作用下混凝土碳化区时空演变规律研究[J].建筑科学与工程学报,2026,(02):86-96.[doi:10.19815/j.jace.2024.10009]
 ZHAO Yanru,LI Long,GUAN He,et al.Research on spatiotemporal evolution patterns of carbonation zones in concrete under combined action of load and carbonation[J].Journal of Architecture and Civil Engineering,2026,(02):86-96.[doi:10.19815/j.jace.2024.10009]
点击复制

荷载与碳化共同作用下混凝土碳化区时空演变规律研究(PDF)
分享到:

《建筑科学与工程学报》[ISSN:1673-2049/CN:61-1442/TU]

卷:
期数:
2026年02期
页码:
86-96
栏目:
建筑材料
出版日期:
2026-03-30

文章信息/Info

Title:
Research on spatiotemporal evolution patterns of carbonation zones in concrete under combined action of load and carbonation
文章编号:
1673-2049(2026)02-0086-11
作者:
赵燕茹1,李龙1,关鹤2,王晓勇3
(1. 内蒙古工业大学 土木工程学院,内蒙古 呼和浩特 010051; 2. 内蒙古工业大学 理学院,内蒙古呼和浩特 010051; 3. 通辽市住房和城乡建设局综合保障中心,内蒙古 通辽 028000)
Author(s):
ZHAO Yanru1, LI Long1, GUAN He2, WANG Xiaoyong3
(1. School of Civil Engineering, Inner Mongolia University of Technology, Hohhot 010051, Inner Mongolia, China; 2. College of Science, Inner Mongolia University of Technology, Hohhot 010051, Inner Mongolia, China; 3. Tongliao City Housing and Urban-rural Development Bureau Comprehensive Security Center, Tongliao 028000, Inner Mongolia, China)
关键词:
混凝土碳化 部分碳化区 CO2扩散修正模型 钢筋锈蚀 弯曲荷载 碳化深度 pH值
Keywords:
concrete carbonation partial carbonation zone CO2 diffusion correction model steel bar corrosion bending load carbonation depth pH value
分类号:
TU528
DOI:
10.19815/j.jace.2024.10009
文献标志码:
A
摘要:
为了解决荷载与碳化共同作用下钢筋的锈蚀问题,首先建立了荷载与碳化共同作用下的CO2扩散修正模型,然后引入与混凝土内部CO2浓度相关联的pH模型,阐述了不同碳化时间与荷载水平下混凝土内部pH值的变化规律,并基于pH值划分混凝土的完全碳化区和部分碳化区范围; 最后利用CO2扩散修正模型预测了混凝土内Ca(OH)2、CaCO3的浓度,研究了各物质浓度与部分碳化区深度的对应关系。结果表明:弯曲荷载与碳化共同作用下,随荷载水平增加,受拉区混凝土pH值降低,Ca(OH)2浓度减小,CaCO3浓度增加,碳化反应更加充分,部分碳化区深度减小; 混凝土受压区pH值升高,Ca(OH)2浓度增加,CaCO3浓度减小,碳化反应速率降低,导致部分碳化区深度增加,促进了部分碳化区的形成; 通过CO2扩散修正模型计算得出pH值为9时对应的碳化深度与酚酞测试得出的碳化深度几乎相等,而pH值为11.5时所对应的深度远大于酚酞测试得出的碳化深度; 当钢筋处于pH值小于11.5的区域时将发生锈蚀,因此在工程中将酚酞测试值作为钢筋保护层厚度并不可靠,应保证混凝土的保护层厚度大于pH值为11.5所对应的碳化深度值,才更科学安全。
Abstract:
In order to solve the problem of steel bar corrosion under the combined action of load and carbonation, a CO2 diffusion correction model under the combined action of load and carbonation was first established. Then, a pH model related to the CO2 concentration inside the concrete was introduced to explain the variation law of pH value inside the concrete under different carbonation time and load levels. Based on the pH value, the complete carbonation zone and partial carbonation zone of concrete were divided. Finally, the concentration of Ca(OH)2 and CaCO3 in concrete was predicted using CO2 diffusion correction model, and the corresponding relationship between the concentration of each substance and the depth of partial carbonation zone was studied. The results show that under the combined action of bending load and carbonation, as the load level increases, the pH value of tensile zone concrete decreases, the concentration of Ca(OH)2 decreases, the concentration of CaCO3 increases, the carbonation reaction becomes more complete, and the depth of partial carbonation zone decreases. The pH value of concrete compression zone increases, the concentration of Ca(OH)2 increases, the concentration of CaCO3 decreases, and the carbonation reaction rate decreases, resulting in an increase in the depth of partial carbonation zone and promoting the formation of partial carbonation zone. The carbonation depth corresponding to pH value of 9 calculated by the CO2 diffusion correction model is almost equal to the carbonation depth obtained by phenolphthalein testing, while the depth corresponding to pH value of 11.5 is much greater than the carbonation depth obtained by phenolphthalein testing. When the steel bars are in the area with a pH value less than 11.5, corrosion will occur. Therefore, using phenolphthalein test values as the thickness of steel bar protective layer in engineering is not reliable. It is necessary to ensure that the thickness of concrete protective layer is greater than the carbonation depth value corresponding to pH value of 11.5 in order to be more scientific and safe.

参考文献/References:

[1] 胡晓龙,肖建庄,上官一宝,等. 海水海砂再生混凝土碳化特性及其低碳潜力[J]. 同济大学学报(自然科学版),2025, 53(8): 1229-1239.
HU Xiaolong, XIAO Jianzhuang, SHANGGUAN Yibao, et al. Carbonation characteristics and low carbon potential of seawater sea sand recycled aggregate concrete[J]. Journal of Tongji University(Natural Science), 2025, 53(8): 1229-1239.
[2]罗小勇,邹洪波,施清亮.不同应力状态下混凝土碳化耐久性试验研究[J].自然灾害学报,2012,21(2):194-199.
LUO Xiaoyong, ZOU Hongbo, SHI Qingliang. Experimental study on durability of concrete carbonation at different stress states[J]. Journal of Natural Disasters, 2012, 21(2): 194-199.
[3]LI D W, LI L Y, WANG X F. Mathematical modelling of concrete carbonation with moving boundary[J]. International Communications in Heat and Mass Transfer, 2020, 117: 104809.
[4]STEINER S, PROSKE T, WINNEFELD F, et al. Effect of limestone fillers on CO2 and water vapour diffusion in carbonated concrete[J]. Cement, 2022, 8: 100027.
[5]ZHANG L, ZHA X X, NING J Q, et al. Research status on the application technology of early age carbon dioxide curing[J]. Buildings, 2023, 13(4): 957.
[6]黎政成. 低热水泥混凝土多场耦合碳化模型与多目标性能设计方法[D]. 哈尔滨: 哈尔滨工业大学, 2024.
LI Zhengcheng. Multi-field coupled carbonization model and multi-objective performance design approach of low-heat cement concrete[D]. Harbin: Harbin Institute of Technology, 2024.
[7]李 蓓.基于水泥水化的水泥基材料热-湿-碳化耦合模型研究[D].杭州:浙江大学,2024.
LI Bei. Research on the heat-moisture-carbonation coupling model of cementitious materials based on hydration theory[D]. Hangzhou: Zhejiang University, 2016.
[8]史鑫宇.荷载与碳化作用下的混凝土损伤分析及碳化深度预测理论模型[D].北京:中国建筑材料科学研究总院,2022.
SHI Xinyu. Damage analysis and theoretical model for carbonation depth prediction of concrete under the combined action of load and carbonation[D]. Beijing: China Building Materials Research Institute, 2022.
[9]李远圣,杜东升,刘伟庆,等.荷载作用下双掺混凝土碳化机理的试验与数值研究[J].混凝土,2017(10):15-19.
LI Yuansheng, DU Dongsheng, LIU Weiqing, et al. Experimental and numerical investigation of carbonation mechanism for concrete with blended admixtures under load[J]. Concrete, 2017(10): 15-19.
[10]夏 冰.混凝土构件再利用与可持续性设计[D].上海:同济大学,2022.
XIA Bing. Reuse and sustainability design of concrete components[D]. Shanghai: Tongji University, 2022.
[11]普通混凝土力学性能试验方法标准:GB/T 50081—2002[S].北京:中国建筑工业出版社,2003.
Standard for test method of mechanical properties on ordinary concrete: GB/T 50081—2002[S].Beijing: China Architecture & Building Press, 2003.
[12]普通混凝土长期性能和耐久性能试验方法标准:GB/T 50082—2009[S].北京:中国建筑工业出版社,2009.
Standard for test methods of long-term performance and durability of ordinary concrete: GB/T 50082—2009[S]. Beijing: China Architecture & Building Press, 2009.
[13]马 超.二氧化碳矿化波特兰水泥浆体动力学与固碳强化研究[D].杭州:浙江大学,2024.
MA Chao. Study on the dynamics and carbon sequestration enhancement of carbon dioxide mineralized Portland cement slurry[D]. Hangzhou: Zhejiang University, 2024.
[14]张玲峰.荷载作用下双掺混凝土碳化机理的试验与数值研究[D].南京:南京工业大学,2015.
ZHANG Lingfeng. Experimental and numerical investigation of carbonation mechanism for concrete with blended admixtures under load[D]. Nanjing: Nanjing University of Technology, 2015.
[15]李 蓓,田 野,金南国,等.基于水泥水化的混凝土碳化深度预测模型[J].水利学报,2015,46(1):109-117.
LI Bei, TIAN Ye, JIN Nanguo, et al. The prediction model of concrete carbonation depth based on cement hydration[J]. Journal of Hydraulic Engineering, 2015, 46(1): 109-117.
[16]曾泽宏.不同养护温度下纳米C—S—H—PCE对水泥浆体水化及微结构演变的影响[D].扬州:扬州大学,2025.
ZENG Zehong. Effect of nano C—S—H—PCE on hydration and microstructural evolution of cement paste under different curing temperatures[D]. Yangzhou: Yangzhou University, 2025.
[17]欧阳威,谢永江,朱长华.大风干旱环境下开裂混凝土碳化过程数值分析[J].铁道建筑,2015,55(6):163-167.
OUYANG Wei, XIE Yongjiang, ZHU Changhua. Numerical analysis of carbonation process in cracked concrete under windy and arid environment[J]. Railway Engineering, 2015, 55(6): 163-167.
[18]金祖权,孙 伟,张云升,等.粉煤灰混凝土的多因素寿命预测模型[J].东南大学学报(自然科学版),2005,35(增1):149-154.
JIN Zuquan, SUN Wei, ZHANG Yunsheng, et al. Multi-factor service life prediction model for concrete with fly ash[J]. Journal of Southeast University(Natural Science Edition), 2005, 35(S1): 149-154.
[19]林其武,章 青,顾 鑫,等.孔隙率和损伤演化加速混凝土碳化的模拟[J].能源与环保,2024,46(5):164-170,180.
LIN Qiwu, ZHANG Qing, GU Xin, et al. Simulation of accelerated carbonation in concrete due to porosity and damage evolution[J]. China Energy and Environmental Protection, 2024, 46(5): 164-170, 180.
[20]GÉRARD B, MARCHAND J. Influence of cracking on the diffusion properties of cement-based materials part I: influence of continuous cracks on the steady-state regime[J]. Cement and Concrete Research, 2000, 30(1): 37-43.
[21]屈志豪.荷载与气压共同作用下高铁隧道衬砌混凝土碳化机理研究[D].重庆:重庆交通大学,2022.
QU Zhihao. Study on carbonization mechanism of high-speed railway tunnel lining under the combined action of load and air pressure[D]. Chongqing: Chongqing Jiaotong University, 2022.
[22]田 浩,李国平,刘 杰,等.受力状态下混凝土试件碳化试验研究[J].同济大学学报(自然科学版),2010,38(2):200-204,213.
TIAN Hao, LI Guoping, LIU Jie, et al. Experimental research on carbonation of forced concrete specimens[J]. Journal of Tongji University(Natural Science), 2010, 38(2): 200-204, 213.
[23]许崇法,曹双寅,范沈龙,等.多因素作用下混凝土中性化深度数值模拟[J].中国公路学报,2014,27(7):60-67.
XU Chongfa, CAO Shuangyin, FAN Shenlong, et al. Numerical simulation for concrete neutralization depth under multiple factors[J]. China Journal of Highway and Transport, 2014, 27(7): 60-67.
[24]罗晓勇.橡胶集料混凝土的高温与碳化性能试验研究[D].泉州:华侨大学,2009.
LUO Xiaoyong. Testing research on the thermal and carbonization properties of crumb rubber concrete[D]. Quanzhou: Huaqiao University, 2009.
[25]尤南乔.模拟海洋环境下碱激发胶凝材料中钢筋腐蚀行为研究[D].南京:东南大学,2021.
YOU Nanqiao. Corrosion behaviour of steel reinforcement in alkali-activated materials under simulated marine environment[D]. Nanjing: Southeast University, 2021.
[26]TWORZEWSKI P, RACZKIEWICZ W, CZAPIK P, et al. Diagnostics of concrete and steel in elements of an historic reinforced concrete structure[J]. Materials, 2021, 14(2): 306.
[27]张 平,王曙光,韩建德,等.静力荷载作用下混凝土抗碳化性能及微观结构演化[J].混凝土,2017(10):45-51.
ZHANG Ping, WANG Shuguang, HAN Jiande, et al. Carbonation resistance and microstructure evolution of concrete under static load test[J]. Concrete, 2017(10): 45-51.
[28]赵燕茹,蔚文豪,王晓勇,等.弯曲荷载作用下混凝土碳化和力学性能研究[J].混凝土,2023(5):27-31.
ZHAO Yanru, YU Wenhao, WANG Xiaoyong, et al. Research on carbonation and mechanical properties of concrete under bending load[J]. Concrete, 2023(5): 27-31.
[29]KOROLEV A S, KOPP A, ODNOBURCEV D, et al. Compressive and tensile elastic properties of concrete: empirical factors in span reinforced structures design[J]. Materials, 2021, 14(24): 7578.
[30]周 健,李伟华,皮振宇,等.硫铝酸盐水泥基材料抗碳化性能研究进展[J].硅酸盐通报,2024,43(8):2711-2725.
ZHOU Jian, LI Weihua, PI Zhenyu, et al. Research progress on carbonation resistance of calcium sulfoaluminate cement-based materials[J]. Bulletin of the Chinese Ceramic Society, 2024, 43(8): 2711-2725.

相似文献/References:

[1]贡金鑫,王振吉,马丽娜,等.沈海高速公路辽宁段沿线桥梁混凝土碳化概率特征研究[J].建筑科学与工程学报,2016,33(05):14.
 GONG Jin-xin,WANG Zhen-ji,MA Li-na,et al.Study on Probability Characteristics of Concrete Carbonation for Bridges of Shenyang-Haikou Highway in Section of Liaoning Province[J].Journal of Architecture and Civil Engineering,2016,33(02):14.

备注/Memo

备注/Memo:
收稿日期:2024-10-06
基金项目:国家自然科学基金项目(12472181,12162025)
作者简介:赵燕茹(1971-),女,工学博士,教授,博士生导师,E-mail:zhaoyanru710523@126.com。
Author resume: ZHAO Yanru(1971-), female, PhD, professor, E-mail: zhaoyanru710523@126.com.
更新日期/Last Update: 2026-04-01