|Table of Contents|

Study on chloride ion diffusion in marine concrete based on long-term exposure test(PDF)

《建筑科学与工程学报》[ISSN:1673-2049/CN:61-1442/TU]

Issue:
2025年04期
Page:
115-123
Research Field:
建筑材料
Publishing date:

Info

Title:
Study on chloride ion diffusion in marine concrete based on long-term exposure test
Author(s):
MA Chuanyi12 QU Guangzhen3 LI Fan12 HUANG Pingming4 SHANG Zhiqiang1 YUAN Yangguang5
(1. Shandong Hi-speed Group Co., Ltd., Jinan 250101, Shandong, China; 2. Shandong Key Laboratory of Highway Technology and Safety Assessment, Jinan 250101, Shandong, China; 3. School of Civil Engineering and Architecture, University of Jinan, Jinan 250022, Shandong, China; 4. School of Highway, Chang'an University, Xi'an 710064, Shaanxi, China; 5. College of Civil Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, Shaanxi, China)
Keywords:
marine concrete long-term exposure test chloride ion diffusion durability life
PACS:
TU375
DOI:
10.19815/j.jace.2023.10014
Abstract:
In order to explore the influence of chloride ion erosion and diffusion on the durability of concrete structures under marine environment, a tracking test was carried out on concrete cube specimens exposed to corrosion for 14 years at Qingdao Jiaozhou Bay bridge exposure station, and the change law of chloride ion concentration of concrete with exposure age in different corrosion areas such as atmospheric area, splash area and water-varying area was analyzed. A time-varying model of chloride ion diffusion coefficient and chloride ion concentration on concrete surface was proposed, and the durability of reinforced concrete under marine environment was predicted. The results show that the chloride ion erosion degree of concrete in the splash area is the most obvious during the exposure period of 14 years. At the exposure age of 1, 5, 14 years, the chloride ion concentration at the depth of 4 mm in the splash area is 7.4 times, 7.6 times and 6.9 times of that in the atmospheric area, respectively. The diffusion coefficient of concrete chloride ion and the surface chloride ion concentration change significantly within 1-3 years of exposure age, and then the change gradually tends to be slow until stable. With the increase of the protective layer thickness, the durability life of the concrete structure against chloride ions gradually increases. The durability life of the concrete structure with the protective layer thickness of 70 mm is about 2 times higher than that with the protective layer thickness of 40 mm. The sensitivity of structural durability life to surface chloride ion concentration, critical chloride ion concentration and protective layer thickness increases in turn. The relevant research can provide reference for the durability design and evaluation of concrete structures in chlorine environment.

References:

[1] 应敬伟,钱邵同,覃盛昆.双轴受压下再生混凝土氯离子扩散规律[J].建筑科学与工程学报,2021,38(2):90-98.
YING Jingwei, QIAN Shaotong, QIN Shengkun. Chloride diffusion law in recycled concrete under biaxial compression[J]. Journal of Architecture and Civil Engineering, 2021, 38(2): 90-98.
[2]TIAN J, WU X W, ZHENG Y, et al. Investigation of damage behaviors of ECC-to-concrete interface and damage prediction model under salt freeze-thaw cycles[J]. Construction and Building Materials, 2019, 226: 238-249.
[3]鲍玖文,庄智杰,张 鹏,等.基于相似性的海洋潮汐区环境混凝土抗氯盐侵蚀性能研究进展[J].材料导报,2021,35(7):7087-7095.
BAO Jiuwen, ZHUANG Zhijie, ZHANG Peng, et al. Research progress of chloride corrosion resistance of concrete exposed to marine tidal environment based on similarity theory[J]. Materials Reports, 2021, 35(7): 7087-7095.
[4]姜凤娇.混凝土水泥水化、氯离子扩散及钢筋锈蚀的电化学分析[D].大连:大连理工大学,2020.
JIANG Fengjiao. Electrochemical analysis of cement hydration, chloride ion diffusion and steel corrosion of concrete[D]. Dalian: Dalian University of Technology, 2020.
[5]WANG Y Z, FU K. Comparisons of instantaneous chloride diffusion coefficients determined by RCM method and chloride natural diffusion test[J]. Construction and Building Materials, 2019, 223: 595-604.
[6]YANG C C, CHO S W, HUANG R. The relationship between charge passed and the chloride-ion concentration in concrete using steady-state chloride migration test[J]. Cement and Concrete Research, 2002, 32(2): 217-222.
[7]混凝土结构耐久性设计与施工指南:CCES 01—2004[S].北京:中国建筑工业出版社,2005.
Guide to durability design and construction of concrete structures: CCES 01—2004[S]. Beijing: China Architecture & Building Press, 2005.
[8]NOSRATZEHI N, MIRI M. Experimental investigation on chloride diffusion coefficient of self-compacting concrete in the Oman sea[J]. Periodica Polytechnica Civil Engineering, 2020: 647-657.
[9]ABABNEH A, BENBOUDJEMA F, XI Y P. Chloride penetration in nonsaturated concrete[J]. Journal of Materials in Civil Engineering, 2003, 15(2): 183-191.
[10]关博文,杨 涛,於德美,等.干湿循环作用下钢筋混凝土氯离子侵蚀与寿命预测[J].材料导报,2016,30(20):152-157.
GUAN Bowen, YANG Tao, YU Demei, et al. Chloride erosion and life prediction of steel reinforced concrete under dry and wet cycles[J]. Materials Reports, 2016, 30(20): 152-157.
[11]陈 昌,杨绿峰,余 波.海洋潮汐区混凝土表面氯离子浓度的时变规律及多因素模型[J].材料导报,2019,33(增2):321-326.
CHEN Chang, YANG Lyufeng, YU Bo. Multi-factor model and time-varying law for surface chloride concentration of concrete in marine tidal zone[J]. Materials Reports, 2019, 33(S2): 321-326.
[12]修建得,金祖权,李 宁,等.海洋盐雾环境下混凝土中氯离子传输研究进展[J].硅酸盐通报,2023,42(3):771-785.
XIU Jiande, JIN Zuquan, LI Ning, et al. Research progress of chloride ion transport in concrete under marine salt spray environment[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(3): 771-785.
[13]陆春华,宋泽鹏,李锺奥,等.氯盐与重复荷载共同作用下海工混凝土梁受弯性能退化分析[J].建筑科学与工程学报,2023,40(5):52-59.
LU Chunhua, SONG Zepeng, LI Zhongao, et al. Degradation analysis of flexural performance of marine concrete beams under combined action of chloride and repeated load[J]. Journal of Architecture and Civil Engineering, 2023, 40(5): 52-59.
[14]王胜年,黎鹏平,范志宏,等.环境和荷载共同作用下的海工混凝土结构耐久性[M].北京:科学出版社,2017.
WANG Shengnian, LI Pengping, FAN Zhihong, et al. Durability of marine concrete structure under the combined action of environment and load[M]. Beijing: Science Press, 2017.
[15]LIU J, LIAO C Y, JIN H S, et al. Numerical model of the effect of water vapor environment on the chloride transport in concrete[J]. Construction and Building Materials, 2021, 311: 125330.
[16]庞 龙,应宗权,范志宏,等.基于实测数据的港工混凝土结构环境荷载模型及耐久性分析[J].工程力学,2016,33(增1):168-172.
PANG Long, YING Zongquan, FAN Zhihong, et al. Environmental load model and durability analysis of harbor concrete structure based on measured data[J]. Engineering Mechanics, 2016, 33(S1): 168-172.
[17]General guidelines for durability design and redesign: DuraCrete BE 95-1347[S]. Denmark: The European Union, 2000.
[18]THOMAS M D A, BENTZ E C.Life-365 computer program for predicting the service life and life-cycle costs of reinforced concrete exposed to chlorides[R]. Farmington Hills: American Concrete Institute, 2000.
[19]金伟良,袁迎曙,卫 军,等.氯盐环境下混凝土结构耐久性理论与设计方法[M].北京:科学出版社,2011.
JIN Weiliang, YUAN Yingshu, WEI Jun, et al. Durability theory and design method of concrete structure in chloride environment[M]. Beijing: Science Press, 2011.
[20]ZHANG H F, ZHANG W P, GU X L, et al. Chloride penetration in concrete under marine atmospheric environment-analysis of the influencing factors[J]. Structure and Infrastructure Engineering, 2016: 1-11.
[21]FIB model code for concrete structures 2010: CEB-FIP[S]. Lausanne: FIB, 2013.
[22]海港工程高性能混凝土质量控制标准:JTS 257-2-2012[S].北京:人民交通出版社,2012.
Quality control standard of high performance concrete for sea port engineering: JTS 257-2-2012[S]. Beijing: China Communications Press, 2012.
[23]杨绿峰,蔡 荣,余 波.海洋大气区混凝土表面氯离子浓度的形成机理和多因素模型[J].土木工程学报,2017,50(12):46-55.
YANG Lufeng, CAI Rong, YU Bo. Formation mechanism and multi-factor model for surface chloride concentration of concrete in marine atmosphere zone[J]. China Civil Engineering Journal, 2017, 50(12): 46-55.
[24]刘玉美,杨 浪,饶 峰,等.氯离子对海工混凝土钢筋腐蚀的研究进展[J].硅酸盐通报,2023,42(9):3059-3074.
LIU Yumei, YANG Lang, RAO Feng, et al. Research progress of chloride ions on corrosion of marine concrete reinforcement[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(9): 3059-3074.
[25]既有混凝土结构耐久性评定标准: GB/T 51355—2019[S]. 北京: 中国建筑工业出版社, 2019.
Evaluation standard for durability of existing concrete structures: GB/T 51355—2019[S]. Beijing: China Architecture & Building Press, 2019.
[26]孙丛涛,刘诗群,牛荻涛,等.干湿循环条件下钢筋锈蚀的临界氯离子浓度[J].建筑材料学报,2016,19(2):385-389.
SUN Congtao, LIU Shiqun, NIU Ditao, et al. Critical chloride concentration of rebar corrosion under dry-wet cycles[J]. Journal of Building Materials, 2016, 19(2): 385-389.
[27]GJORV O E. 严酷环境下混凝土结构的耐久性设计[M].赵铁军,译.2版.北京:中国建材工业出版社,2015.
GJORV O E. Durability design of concrete structures in severe environments[M]. Translated by ZHAO Tiejun, 2nd ed. Beijing: China Building Material Press, 2015.

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Last Update: 2025-07-10